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Thermal cracking process in oil refining
In petrochemistry, petroleum geology and organic chemistry, 'cracking' is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of a large alkane into smaller, more useful alkenes. Simply put, hydrocarbon cracking is the process of breaking a long chain of hydrocarbons into short ones. This process requires high temperatures.
More loosely, outside the field of petroleum chemistry, the term "cracking" is used to describe any type of splitting of molecules under the influence of heat, catalysts and solvents, such as in processes of destructive distillation or pyrolysis.
Fluid catalytic cracking produces a high yield of petrol and liquefied petroleum gas (LPG), while hydrocracking is a major source of jet fuel, diesel fuel, naphtha, and again yields LPG.